Origin of Tertiary to Recent EM- and subduction-like chemical and isotopic signatures in Auca Mahuida region (37°–38°S) and other Patagonian plateau lavas     

Suzanne Mahlburg Kay  Helen A. Jones  Robert W. Kay 《Contributions to Mineralogy and Petrology》2013,166(1):165-192

The alkaline volcanic rocks of the 1.8–0.9 Ma Auca Mahuida and post-mid-Pliocene Rio Colorado backarc volcanic fields east of the Andean Southern Volcanic Zone at ~37°–38°S have pronounced intraplate-like chemical signatures with some striking similarities to oceanic DM-EM1-like lavas of the south Atlantic Tristan da Cunha type. These backarc lavas are considered to have formed as a series of mantle batches typified by 4–7 % melting, with decompression melting initiating in a garnet-bearing mantle above a steepening subduction zone, and final equilibration occurring near the base of a ~65- to 70-km-thick lithosphere at temperatures of ~1,350–1,380 °C. Evolved Auca Mahuida mugearite to trachytic samples are best explained by crystal fractionation with limited mixing of partial melts of recently underplated basalts, in line with isotopic signatures that preclude significant radiogenic contamination in a preexisting refractory crust. Higher Ba/La and subtly higher La/Ta ratios than in nearby ~24–20 Ma primitive basalts or oceanic (OIB) lavas are attributed to the residual effects of slab fluids introduced during a shallow subduction episode recorded in the arc-like chemistry of the adjacent 7–4 Ma Chachahuén volcanic complex. Positive Sr, K and Ba spikes on mantle-normalized patterns of both primitive Auca Mahuida and ~24–20 Ma basalts, like those in EM-like OIB basalts, are attributed to mixing of continental lithosphere into the asthenosphere. In Patagonia, this mixing is suggested to have peaked as the South America continent accommodated to major late Oligocene plate convergence changes, as similar Sr, K and Ba spikes and DM-EM1 signatures are absent in ~50–30 Ma backarc lavas north of 51°S, and all of those south of 51°S. Introduction of an EM1-like component associated with lateral mantle flow of a Tristan da Cunha source is largely precluded by its Cretaceous age and distance to Patagonia.  相似文献   

Assessing Nitrogen Dynamics Throughout the Estuarine Landscape     

Ashley R. Smyth  Suzanne P. Thompson  Kaylyn N. Siporin  Wayne S. Gardner  Mark J. McCarthy  Michael F. Piehler 《Estuaries and Coasts》2013,36(1):44-55

Assessing nitrogen dynamics in the estuarine landscape is challenging given the unique effects of individual habitats on nitrogen dynamics. We measured net N₂ fluxes, sediment oxygen demand, and fluxes of ammonium and nitrate seasonally from five major estuarine habitats: salt marshes, seagrass beds (SAV), oyster reefs, and intertidal and subtidal flats. Net N₂ fluxes ranged from 332?±?116 μmol?N-N₂?m^?2?h^?1 from oyster reef sediments in the summer to ?67?±?4 μmol?N-N₂?m^?2?h^?1 from SAV in the winter. Oyster reef sediments had the highest rate of N₂ production of all habitats. Dissimilatory nitrate reduction to ammonium (DNRA) was measured during the summer and winter. DNRA was low during the winter and ranged from 4.5?±?3.0 in subtidal flats to 104?±?34 μmol?¹⁵NH ₄ ⁺ ?m^?2?h^?1 in oyster reefs during the summer. Annual denitrification, accounting for seasonal differences in inundation and light, ranged from 161.1?±?19.2 mmol?N-N₂?m^?2?year^?1 for marsh sediments to 509.9?±?122.7 mmol?N-N₂?m^?2?year^?1 for SAV sediments. Given the current habitat distribution in our study system, an estimated 28.3?×?10⁶?mol of N are removed per year or 76 % of estimated watershed nitrogen load. These results indicate that changes in the area and distribution of habitats in the estuarine landscape will impact ecosystem function and services.  相似文献   

Pyrite paragenesis and multiple sulfur isotope distribution in late Archean and early Paleoproterozoic Hamersley Basin sediments   总被引：1，自引：0，他引：1  

Michaela A. Partridge  Suzanne D. Golding  Kim A. Baublys  Elisa Young 《Earth and Planetary Science Letters》2008,272(1-2):41-49

The sulfur isotope record in late Archean and early Paleoproterozoic rocks is of considerable importance because it provides evidence for changes in early Earth atmospheric oxygen levels and potentially constrains the origin and relative impact of various microbial metabolisms during the transition from an anoxic to oxic atmosphere. Mass independently fractionated (MIF) sulfur isotopes reveal late Archean and early Paleoproterozoic sulfur sources in different pyrite morphologies in Western Australia's Hamersley Basin. Multiple sulfur isotope values in late Archean pyrite vary according to morphology. Fine grained pyrite has positive sulfur MIF, indicating a reduced elemental sulfur source, whereas pyrite nodules have negative sulfur MIF, potentially derived from soluble sulfate via microbial sulfate reduction. The Hamersley Basin δ³⁴S–Δ³³S record suggests that the extent of oxygenation of the surface ocean fluctuated through the Late Archean from at least 2.6 Ga, more than 150 million yr before the Great Oxidation Event. In the early Paleoproterozoic, there is less distinction between pyrite morphologies with respect to sulfur isotope fractionation, and pyrite from the Brockman Iron Formation trends toward modern sulfur isotope values. An important exception to this is the strong negative MIF recorded in layer parallel pyrite in Paleoproterozoic carbonate facies iron formation. This may suggest that deeper water hydrothermal environments remained anoxic while shallower water environments became more oxidised by the early Paleoproterozoic. The results of the current study indicate that sulfide paragenesis is highly significant when investigating Archean and early Paleoproterozoic multiple sulfur isotope compositions and sulfur sources.  相似文献   

Overview of integrative tools and methods in assessing ecological integrity in estuarine and coastal systems worldwide   总被引：9，自引：1，他引：8  

Borja A  Bricker SB  Dauer DM  Demetriades NT  Ferreira JG  Forbes AT  Hutchings P  Jia X  Kenchington R  Carlos Marques J  Zhu C 《Marine pollution bulletin》2008,56(9):1519-1537

In recent years, several sets of legislation worldwide (Oceans Act in USA, Australia or Canada; Water Framework Directive or Marine Strategy in Europe, National Water Act in South Africa, etc.) have been developed in order to address ecological quality or integrity, within estuarine and coastal systems. Most such legislation seeks to define quality in an integrative way, by using several biological elements, together with physico-chemical and pollution elements. Such an approach allows assessment of ecological status at the ecosystem level ('ecosystem approach' or 'holistic approach' methodologies), rather than at species level (e.g. mussel biomonitoring or Mussel Watch) or just at chemical level (i.e. quality objectives) alone. Increasing attention has been paid to the development of tools for different physico-chemical or biological (phytoplankton, zooplankton, benthos, algae, phanerogams, fishes) elements of the ecosystems. However, few methodologies integrate all the elements into a single evaluation of a water body. The need for such integrative tools to assess ecosystem quality is very important, both from a scientific and stakeholder point of view. Politicians and managers need information from simple and pragmatic, but scientifically sound methodologies, in order to show to society the evolution of a zone (estuary, coastal area, etc.), taking into account human pressures or recovery processes. These approaches include: (i) multidisciplinarity, inherent in the teams involved in their implementation; (ii) integration of biotic and abiotic factors; (iii) accurate and validated methods in determining ecological integrity; and (iv) adequate indicators to follow the evolution of the monitored ecosystems. While some countries increasingly use the establishment of marine parks to conserve marine biodiversity and ecological integrity, there is awareness (e.g. in Australia) that conservation and management of marine ecosystems cannot be restricted to Marine Protected Areas but must include areas outside such reserves. This contribution reviews the current situation of integrative ecological assessment worldwide, by presenting several examples from each of the continents: Africa, Asia, Australia, Europe and North America.  相似文献   

Quantifying preferential flow in soils: A review of different techniques   总被引：19，自引：0，他引：19  

Suzanne E. Allaire  Stphanie Roulier  Allan J. Cessna 《Journal of Hydrology》2009,378(1-2):179-204

Preferential flow (PF) in soil has both environmental and human health implications since it favours contaminant transport to groundwater without interaction with the chemically and biologically reactive upper layer of soil. PF is, however, difficult to measure and quantify. This paper reviews laboratory and field techniques, such as breakthrough curves, dye tracing, and scanning techniques, for evaluating PF in soil at different scales. Advanced technologies, such as scanning techniques, have increased our capability to quantify transport processes within the soil with minimal soil disturbance. Important issues with respect to quantifying PF concern large-scale studies, frozen soil conditions, tracing techniques for particles and gases, a lack of simple mathematical tools for interpreting field data, and the lack of a systematic approach for comparing PF data resulting from different measurement techniques. Also, more research is required to quantify the relative importance of the various PF processes that occur in soil rather than the integrated result of all PF processes in soils.  相似文献   

Recent water quality trends and a comparison to sediment-core records for two riverine lakes of the Upper Mississippi River basin: Lake St. Croix and Lake Pepin     

Brenda Moraska Lafrancois  Suzanne Magdalene  D. Kent Johnson 《Journal of Paleolimnology》2009,41(4):603-622

Long-term water quality monitoring data from two riverine lakes in the Upper Mississippi River basin, Lakes St. Croix and Pepin, were analyzed to compare the long-term average water quality conditions and land use distributions, water quality trends and loads at lake inlets and outlets, trends from long-term versus short-term monitoring records, and the ability of paleolimnological cores to accurately infer lake water quality conditions. During the 1976–2004 period, the long-term average concentrations of nutrients, suspended solids, and chlorophyll-a were consistently lower at the Lake St. Croix inlet versus the Lake Pepin inlet, which drains a greater proportion of urban and agricultural runoff. Despite these differences, nutrient trends were similar at the inlets to both lakes; reductions in total phosphorus and ammonium concentrations were attributed to improvements in point source technologies, whereas increasing nitrate concentrations were attributed to both point source changes and nonpoint source increases. Despite improvements in several water quality variables, nitrate concentrations are increasing in both lakes, sediment trends indicate persistent nonpoint source inputs to Lake Pepin, and current total phosphorus concentrations remain well above pre-1950s levels in both lakes. Since urban development and agriculture are increasing in the Lake St. Croix and Lake Pepin Watersheds, continued point source regulation and additional nonpoint source control efforts will be needed to further improve water quality in these lakes. The 1976–2004 trends for most water quality variables were similar at inlet versus outlet sites on Lake St. Croix. Trends at Lake Pepin inlet versus outlet sites were less similar, but data availability limited the comparison to the 1993–2003 period. While the truncated data record highlighted short-term trends in both lakes, the full data record was most useful for exploring general patterns in water quality. Length of monitoring record affected our ability to detect trends at the inlets to both lakes, and altered the magnitude of detected trends. During the two decades of the 1980s and 1990s, paleolimnological estimates of retained phosphorus loads were similar to those estimated from recent water quality monitoring. These similarities support the use of paleolimnological approaches to infer past water quality conditions in Lakes St. Croix and Pepin. This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue.  相似文献   

Carbonatite metasomatized peridotite xenoliths from southern Patagonia: implications for lithospheric processes and Neogene plateau magmatism   总被引：10，自引：0，他引：10  

Matthew L. Gorring  Suzanne M. Kay 《Contributions to Mineralogy and Petrology》2000,140(1):55-72

The mineral chemistry, major and trace element, and Sr–Nd isotopic composition of Cr-diopside, spinel peridotite xenoliths from the Estancia Lote 17 locality in southern Patagonia document a strong carbonatitic metasomatism of the backarc continental lithosphere. The Lote 17 peridotite xenolith suite consists of hydrous spinel lherzolite, wehrlite, and olivine websterite, and anhydrous harzburgite and lherzolite. Two-pyroxene thermometry indicates equilibration temperatures ranging from 870 to 1015 °C and the lack of plagioclase or garnet suggests the xenoliths originated from between ˜40 and 60 km depth. All of the xenoliths are LILE- and LREE-enriched, but have relatively low ⁸⁷Sr/⁸⁶Sr (0.70294 to 0.70342) and high ɛ_Nd (+3.0 to +6.6), indicating recent trace element enrichment (∼25 Ma, based on the low ⁸⁷Sr/⁸⁶Sr and high Rb concentrations of phlogopite separates) in the long-term, melt-depleted Patagonian lithosphere. Lote 17 peridotite xenoliths are divided into two basic groups. Group 1 xenoliths consist of fertile peridotites that contain hydrous phases (amphibole ± phlogopite ± apatite). Group 1 xenoliths are further subdivided into three groups (a, b, and c) based on distinctive textures and whole-rock chemistry. Group 1 xenolith mineralogy and chemistry are consistent with a complex metasomatic history involving variable extents of recent carbonatite metasomatism (high Ca/Al, Nb/La, Zr/Hf, low Ti/Eu) that has overprinted earlier metasomatic events. Group 2 xenoliths consist of infertile, anhydrous harzburgites and record cryptic metasomatism that is attributed to CO₂-rich fluids liberated from Group 1 carbonatite metasomatic reactions. Extremely variable incompatible trace element ratios and depleted Sr–Nd isotopic compositions of Lote 17 peridotite xenoliths indicate that the continental lithosphere was neither the primary source nor an enriched lithospheric contaminant for Neogene Patagonian plateau lavas. Neogene plateau magmatism associated with formation of asthenospheric slab windows may have triggered this occurrence of “intraplate-type” carbonatite metasomatism in an active continental backarc setting. Received: 26 January 2000 / Accepted: 1 March 2000  相似文献   

Morphodynamic assessment of side channel systems using a simple one‐dimensional bifurcation model and a comparison with aerial images          下载免费PDF全文

R. Pepijn van Denderen  Ralph M. J. Schielen  Astrid Blom  Suzanne J. M. H. Hulscher  Maarten G. Kleinhans 《地球表面变化过程与地形》2018,43(6):1169-1182

Side channel construction is a common intervention applied to increase a river's conveyance capacity and to increase its ecological value. Past modelling efforts suggest two mechanisms affecting the morphodynamic change of a side channel: (1) a difference in channel slope between the side channel and the main channel and (2) bend flow just upstream of the bifurcation. The objective of this paper was to assess the conditions under which side channels generally aggrade or degrade and to assess the characteristic timescales of the associated morphological change. We use a one‐dimensional bifurcation model to predict the development of side channel systems and the characteristic timescale for a wide range of conditions. We then compare these results to multitemporal aerial images of four side channel systems. We consider the following mechanisms at the bifurcation to be important for side channel development: sediment diversion due to the bifurcation angle, sediment diversion due to the transverse bed slope, partitioning of suspended load, mixed sediment processes such as sorting at the bifurcation, bank erosion, deposition due to vegetation, and floodplain sedimentation. There are limitations to using a one‐dimensional numerical model as it can only account for these mechanisms in a parametrized manner, but the model reproduces general behaviour of the natural side channels until floodplain‐forming processes become important. The main result is a set of stability diagrams with key model parameters that can be used to assess the development of a side channel system and the associated timescale, which will aid in the future design and maintenance of side channel systems. © 2017 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

Strong variation in weathering of layered rock maintains hillslope‐scale strength under high precipitation          下载免费PDF全文

Jennifer Von Voigtlander  Marin K. Clark  Dimitrios Zekkos  William W. Greenwood  Suzanne P. Anderson  Robert S. Anderson  Jonathan W. Godt 《地球表面变化过程与地形》2018,43(6):1183-1194

The evolution of volcanic landscapes and their landslide potential are both dependent upon the weathering of layered volcanic rock sequences. We characterize critical zone structure using shallow seismic V_p and V_s profiles and vertical exposures of rock across a basaltic climosequence on Kohala peninsula, Hawai’i, and exploit the dramatic gradient in mean annual precipitation (MAP) across the peninsula as a proxy for weathering intensity. Seismic velocity increases rapidly with depth and the velocity–depth gradient is uniform across three sites with 500–600 mm/yr MAP, where the transition to unaltered bedrock occurs at a depth of 4 to 10 m. In contrast, velocity increases with depth less rapidly at wetter sites, but this gradient remains constant across increasing MAP from 1000 to 3000 mm/yr and the transition to unaltered bedrock is near the maximum depth of investigation (15–25 m). In detail, the profiles of seismic velocity and of weathering at wet sites are nowhere monotonic functions of depth. The uniform average velocity gradient and the greater depths of low velocities may be explained by the averaging of velocities over intercalated highly weathered sites with less weathered layers at sites where MAP > 1000 mm/yr. Hence, the main effect of climate is not the progressive deepening of a near‐surface altered layer, but rather the rapid weathering of high permeability zones within rock subjected to precipitation greater than ~1000 mm/yr. Although weathering suggests mechanical weakening, the nearly horizontal orientation of alternating weathered and unweathered horizons with respect to topography also plays a role in the slope stability of these heterogeneous rock masses. We speculate that where steep, rapidly evolving hillslopes exist, the sub‐horizontal orientation of weak/strong horizons allows such sites to remain nearly as strong as their less weathered counterparts at drier sites, as is exemplified by the 50°–60° slopes maintained in the amphitheater canyons on the northwest flank of the island. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Ecosystem engineering by hummock-building earthworms in seasonal wetlands of eastern South Africa: Insights into the mechanics of biomorphodynamic feedbacks in wetland ecosystems     

Michael C. Grenfell  Rolf Aalto  Suzanne E. Grenfell  William N. Ellery 《地球表面变化过程与地形》2019,44(1):354-366

This paper resolves the origin of clay hummock micro-topography in seasonal wetlands of the Drakensberg Foothills, providing a review and appraisal of previously-suggested mechanisms of hummock formation in the context of new field and laboratory data. Field surveys revealed neo-formation of clay hummocks in a river channel that had been abandoned in c.1984. Fresh earthworm castings were located atop hummocks protruding from inundated abandoned channel margins. Earthworm castings, and sediment cores taken in hummocks and adjacent hollows, were analysed for soil-adsorbed carbon and nitrogen using an HCN analyser, and for ²¹⁰Pb activity using alpha-geochronology. ²¹⁰Pb activity profiles suggest relative enrichment of the isotope in hummocks, and relative depletion in adjacent hollows. Earthworm castings are characterised by very high ²¹⁰Pb activity, as well as high C and N contents. Hummocks have significantly higher C and N contents than adjacent hollows. Results suggest that it is the foraging activity of earthworms in litter-rich seasonal wetland hollows, and repeated excretion of castings atop adjacent hummocks, that is responsible for the elemental enrichment observed. The paper presents a conceptual model of hummock formation in wetlands through interactions between hydrogeomorphology and earthworm activity, and illustrates a mechanism of biogeomorphic inheritance through which ordered patterns of preferential flow can emerge in ecosystems. Further implications of hummock formation and nodal accumulation of nutrients are considered in relation to wetland resilience and regulatory ecosystem service provision.© 2018 John Wiley & Sons, Ltd.  相似文献